Screening test programmes for reactive hazard characterisation
Reactive screening test programmes evaluate exothermic potential, water reactivity, and incompatibility through structured laboratory protocols. Results feed safe handling decisions, storage segregation, and process design margins.
A structured, facilitated process — from scope definition through close-out — producing defensible, actionable outputs.
Conduct literature screening per CCPS Reactive Chemicals — Bretherick's Handbook, Yoshida structural alerts, NOAA Chemical Reactivity Worksheet; identify reactive functional groups (peroxide, azide, nitro, diazo, acetylide, fulminate).
Apply CHETAH (Chemical Thermodynamic and Energy Hazard) algorithm — calculate maximum decomposition heat (ΔHdec), oxygen balance, and energy release index; align with ASTM CHETAH protocol and CCPS guidance.
Conduct DSC per ASTM E537 / E2046 with controlled atmosphere (N₂ / air / O₂) — temperature ramp 5-10°C/min; identify exothermic onset, peak, and energy release; align with EFCE / IChemE screening protocol.
Conduct binary compatibility screening for each material pair in intentional contact or credible mixing scenarios; align with OSHA PSM Process Safety Information / CCPS Inherent Safer Reactive Hazard avoidance.
Classify material per Stoessel scenario class (1-5) and CCPS Reactive Chemicals hazard tier; risk-rank for further testing (calorimetry, RC1 reactor, vent sizing); align with OSHA PSM Reactive Hazard programme.
Compile reactive screening dossier with literature review, CHETAH output, DSC trace, compatibility matrix; integrate with Reactive Hazard Programme, HAZOP / SIL allocation, and OSHA PSM Process Safety Information.
Speak with our team to scope an engagement tailored to your facility, regulatory context, and lifecycle stage.